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dc.creatorQuiroga, Monica Esther-
dc.creatorLiprandi, Domingo Antonio-
dc.creatorCagnola, Edgardo Alberto-
dc.creatorL' Argentière, P.C.-
dc.date2018-11-27T16:59:18Z-
dc.date2018-11-27T16:59:18Z-
dc.date2007-07-
dc.date2018-11-22T14:26:46Z-
dc.date.accessioned2019-04-29T15:48:57Z-
dc.date.available2019-04-29T15:48:57Z-
dc.date.issued2007-07-
dc.identifierQuiroga, Monica Esther; Liprandi, Domingo Antonio; Cagnola, Edgardo Alberto; L' Argentière, P.C.; 1-Heptyne semihydrogenation catalized by palladium or rhodium complexes. Influence of: metal atom, ligands and the homo/heterogeneous condition; Elsevier Science; Applied Catalysis A: General; 326; 2; 7-2007; 121-129-
dc.identifier0926-860X-
dc.identifierhttp://hdl.handle.net/11336/65324-
dc.identifierCONICET Digital-
dc.identifierCONICET-
dc.identifier.urihttp://rodna.bn.gov.ar:8080/jspui/handle/bnmm/302792-
dc.description[RhCl(TDA)3], [RhCl(HA)3], [PdCl2(TDA)2] and [PdCl2(HA)2] (TDA = tridecylamine, HA = hexylamine) were synthesized and tested as catalysts in homogeneous and heterogeneous condition for the 1-heptyne semihydrogenation, using γ-alumina as support. The Lindlar catalyst was used as a reference. XPS, FTIR and Atomic Absorption results showed that the active catalytic species in each case is the complex itself. All of the catalytic systems exhibited a better performance than the Lindlar catalyst, with the exception of [PdCl2(HA)2]. The analysis of activity and selectivity values allowed to say that the best system is [RhCl(TDA)3]/Al2O3, an heterogeneous catalyst with an electron-rich transition metal and an electron-donating ligand (TDA) containing a long-chain hydrocarbon substituent. The complex system catalytic behaviour could be explained by means of electronic and geometric effects.-
dc.descriptionFil: Quiroga, Monica Esther. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina-
dc.descriptionFil: Liprandi, Domingo Antonio. Universidad Nacional del Litoral; Argentina-
dc.descriptionFil: Cagnola, Edgardo Alberto. Universidad Nacional del Litoral; Argentina-
dc.descriptionFil: L' Argentière, P.C.. Universidad Nacional del Litoral; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina-
dc.formatapplication/pdf-
dc.formatapplication/pdf-
dc.formatapplication/pdf-
dc.formatapplication/pdf-
dc.formatapplication/pdf-
dc.languageeng-
dc.publisherElsevier Science-
dc.relationinfo:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.apcata.2007.03.035-
dc.rightsinfo:eu-repo/semantics/restrictedAccess-
dc.rightshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/-
dc.sourcereponame:CONICET Digital (CONICET)-
dc.sourceinstname:Consejo Nacional de Investigaciones Científicas y Técnicas-
dc.sourceinstacron:CONICET-
dc.subject1-HEPTYNE SEMIHYDROGENATION-
dc.subjectRh/Pd COMPLEXES-
dc.subjectCOORDINATION SPHERE-
dc.subjectHOMO/HETEROGENEUS CONDITION-
dc.subjectOtras Ingeniería Química-
dc.subjectIngeniería Química-
dc.subjectINGENIERÍAS Y TECNOLOGÍAS-
dc.title1-Heptyne semihydrogenation catalized by palladium or rhodium complexes. Influence of: metal atom, ligands and the homo/heterogeneous condition-
dc.typeinfo:eu-repo/semantics/article-
dc.typeinfo:eu-repo/semantics/publishedVersion-
dc.typeinfo:ar-repo/semantics/articulo-
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