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dc.provenanceCONICET-
dc.creatorMassimi, Lorenzo-
dc.creatorAngelucci, Marco-
dc.creatorGargiani, Perluigi-
dc.creatorBetti, Maria Grazia-
dc.creatorMontoro, Silvia Susana-
dc.creatorMariani, Carlo-
dc.date2016-12-20T21:20:35Z-
dc.date2016-12-20T21:20:35Z-
dc.date2014-06-
dc.date2016-11-23T20:16:12Z-
dc.date.accessioned2019-04-29T15:41:44Z-
dc.date.available2019-04-29T15:41:44Z-
dc.date.issued2014-06-
dc.identifierMassimi, Lorenzo; Angelucci, Marco; Gargiani, Perluigi; Betti, Maria Grazia; Montoro, Silvia Susana; et al.; Metal-phthalocyanine ordered layers on Au(110): Metal-dependent adsorption energy; American Institute Of Physics; Journal Of Chemical Physics; 140; 6-2014; 2447041-2447048-
dc.identifier0021-9606-
dc.identifierhttp://hdl.handle.net/11336/9875-
dc.identifier.urihttp://rodna.bn.gov.ar:8080/jspui/handle/bnmm/299757-
dc.descriptionIron-phthalocyanine and cobalt-phthalocyanine chains, assembled along the Au(110)-(1×2) reconstructed channels, present a strong interaction with the Au metallic states, via the central metal ion. X-ray photoemission spectroscopy from the metal-2p core-levels and valence band high-resolution ultraviolet photoelectron spectroscopy bring to light signatures of the interaction of the metalphthalocyanine single-layer with gold. The charge transfer from Au to the molecule causes the emerging of a metal-2p core level component at lower binding energy with respect to that measured in the molecular thin films, while the core-levels associated to the organic macrocycle (C and N 1s) are less influenced by the adsorption, and the macrocycles stabilize the interaction, inducing a strong interface dipole. Temperature Programmed Desorption experiments and photoemission as a function of temperature allow to estimate the adsorption energy for the thin-films, mainly due to the moleculemolecule van der Waals interaction, while the FePc and CoPc single-layers remain adsorbed on the Au surface up to at least 820 K. © 2014 AIP Publishing LLC.-
dc.descriptionFil: Massimi, Lorenzo. Universita Di Roma. Departamento de Fisica; Italia-
dc.descriptionFil: Angelucci, Marco. Universita Di Roma. Departamento de Fisica; Italia-
dc.descriptionFil: Gargiani, Perluigi. Universita Di Roma. Departamento de Fisica; Italia-
dc.descriptionFil: Betti, Maria Grazia. Universita Di Roma. Departamento de Fisica; Italia-
dc.descriptionFil: Montoro, Silvia Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe. Instituto de Física del Litoral; Argentina-
dc.descriptionFil: Mariani, Carlo. Universita Di Roma. Departamento de Fisica; Italia-
dc.formatapplication/pdf-
dc.formatapplication/pdf-
dc.languageeng-
dc.publisherAmerican Institute Of Physics-
dc.relationinfo:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1063/1.4883735-
dc.relationinfo:eu-repo/semantics/altIdentifier/url/http://aip.scitation.org/doi/full/10.1063/1.4883735-
dc.rightsinfo:eu-repo/semantics/openAccess-
dc.rightshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/-
dc.sourcereponame:CONICET Digital (CONICET)-
dc.sourceinstname:Consejo Nacional de Investigaciones Científicas y Técnicas-
dc.sourceinstacron:CONICET-
dc.source.urihttp://hdl.handle.net/11336/9875-
dc.subjectMetal-phthalocyanine-
dc.subjectX-ray photoemission-
dc.subjectDesorption-
dc.subjectadsorption energy-
dc.subjectFísica Atómica, Molecular y Química-
dc.subjectCiencias Físicas-
dc.subjectCIENCIAS NATURALES Y EXACTAS-
dc.titleMetal-phthalocyanine ordered layers on Au(110): Metal-dependent adsorption energy-
dc.typeinfo:eu-repo/semantics/article-
dc.typeinfo:eu-repo/semantics/publishedVersion-
dc.typeinfo:ar-repo/semantics/articulo-
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