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dc.provenanceCONICET-
dc.creatorBlanco, Maria Belen-
dc.creatorTeruel, Mariano Andres-
dc.date2019-01-04T12:40:52Z-
dc.date2019-01-04T12:40:52Z-
dc.date2011-01-
dc.date2019-01-02T19:10:59Z-
dc.date.accessioned2019-04-29T15:41:28Z-
dc.date.available2019-04-29T15:41:28Z-
dc.date.issued2019-01-04T12:40:52Z-
dc.date.issued2019-01-04T12:40:52Z-
dc.date.issued2011-01-
dc.date.issued2019-01-02T19:10:59Z-
dc.identifierBlanco, Maria Belen; Teruel, Mariano Andres; Atmospheric photodegradation of ethyl vinyl ketone and vinyl propionate initiated by OH radicals; Elsevier Science; Chemical Physics Letters; 502; 4-6; 1-2011; 159-162-
dc.identifier0009-2614-
dc.identifierhttp://hdl.handle.net/11336/67371-
dc.identifierCONICET Digital-
dc.identifierCONICET-
dc.identifier.urihttp://rodna.bn.gov.ar:8080/jspui/handle/bnmm/299629-
dc.descriptionRate coefficients for the reactions of hydroxyl radicals with ethyl vinyl ketone and vinyl propionate were determined at 298 K and atmospheric pressure. A collapsible chamber with gas chromatography was used to perform relative kinetic determinations. The room temperature rate coefficients (in cm 3 molecule-1 s-1) were: k1(OH + CH2CHC(O)CH2CH3) = (2.90 ± 0.79) × 10-11 and k2(OH + CH2CHOC(O)CH 2CH3) = (2.46 ± 0.28) × 10-11. This is the first kinetic study of title reactions under atmospheric conditions. The kinetic data were compared with previous literature values, used to calculate atmospheric lifetimes and correlated with the ionization potential of the unsaturated compounds. © 2010 Elsevier B.V. All rights reserved.-
dc.descriptionFil: Blanco, Maria Belen. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina-
dc.descriptionFil: Teruel, Mariano Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina-
dc.formatapplication/pdf-
dc.formatapplication/pdf-
dc.formatapplication/pdf-
dc.languageeng-
dc.publisherElsevier Science-
dc.relationinfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0009261410016465-
dc.relationinfo:eu-repo/semantics/altIdentifier/doi/http://dx.doi.org/10.1016/j.cplett.2010.12.059-
dc.rightsinfo:eu-repo/semantics/restrictedAccess-
dc.rightshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/-
dc.sourcereponame:CONICET Digital (CONICET)-
dc.sourceinstname:Consejo Nacional de Investigaciones Científicas y Técnicas-
dc.sourceinstacron:CONICET-
dc.source.urihttp://hdl.handle.net/11336/67371-
dc.subjectRELATIVE KINETICS-
dc.subjectUNSATURATED VOCs-
dc.subjectSIMULATION CHAMBERS-
dc.subjectOH RADICALS-
dc.subjectOtras Ciencias Químicas-
dc.subjectCiencias Químicas-
dc.subjectCIENCIAS NATURALES Y EXACTAS-
dc.titleAtmospheric photodegradation of ethyl vinyl ketone and vinyl propionate initiated by OH radicals-
dc.typeinfo:eu-repo/semantics/article-
dc.typeinfo:eu-repo/semantics/publishedVersion-
dc.typeinfo:ar-repo/semantics/articulo-
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