Registro completo de metadatos
| Campo DC | Valor | Lengua/Idioma |
|---|---|---|
| dc.creator | Borsarelli, Claudio Darío | - |
| dc.creator | Braslavsky, Silvia E. | - |
| dc.creator | Indelli, María Teresa | - |
| dc.creator | Scandola, Franco | - |
| dc.date | 2019-03-14T19:29:15Z | - |
| dc.date | 2019-03-14T19:29:15Z | - |
| dc.date | 2000-01 | - |
| dc.date | 2019-03-14T14:17:47Z | - |
| dc.date.accessioned | 2019-04-29T15:27:49Z | - |
| dc.date.available | 2019-04-29T15:27:49Z | - |
| dc.date.issued | 2019-03-14T19:29:15Z | - |
| dc.date.issued | 2019-03-14T19:29:15Z | - |
| dc.date.issued | 2000-01 | - |
| dc.date.issued | 2019-03-14T14:17:47Z | - |
| dc.identifier | Borsarelli, Claudio Darío; Braslavsky, Silvia E.; Indelli, María Teresa; Scandola, Franco; Photophysics of supercomplexes. a laser-induced optoacoustic study of the adducts between Ru(bpy)(CN)4 2- and polyaza macrocycles; Elsevier Science; Chemical Physics Letters; 317; 1-2; 1-2000; 53-58 | - |
| dc.identifier | 0009-2614 | - |
| dc.identifier | http://hdl.handle.net/11336/71686 | - |
| dc.identifier | CONICET Digital | - |
| dc.identifier | CONICET | - |
| dc.identifier.uri | http://rodna.bn.gov.ar:8080/jspui/handle/bnmm/294604 | - |
| dc.description | In aqueous solution, the energy content of the triplet metal-to-ligand charge transfer (3MLCT) state, as determined by laser-induced optoacoustic spectroscopy, for both 1:1 supercomplexes {[Ru(bpy)(CN)4]·[24]ane-[N6H6]} 4+ and {[Ru(bpy)(CN)4]·[32]ane-[N8H8]} 6+ are similar to that for free Ru(bpy)(CN)4 2- (223±8 kJ/mol). The reduction of the structural volume change upon formation of the 3MLCT state in the order Ru(bpy)(CN)4 2- (14.9 ml/mol), {[Ru(bpy)(CN)4]·[32]ane-[N8H8]} 6+ (5.2 ml/mol) and {[Ru(bpy)(CN)4]·[24]ane-[N6H6]} 4+ (2.5 ml/mol) is attributed to the rigidity of the macrocycle cavity. The 3MLCT state lifetime increase from 104 ns for Ru(bpy)(CN)4 2- to 150 ns for {[Ru(bpy)(CN)4]·[24]ane-[N6H6]} 4+ and 182 ns for {[Ru(bpy)(CN)4]·[32]ane-[N8H8]} 6+ is due to the decrease in the number of CN groups free to form hydrogen bonds with water: four, one, and none, respectively. | - |
| dc.description | Fil: Borsarelli, Claudio Darío. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Gobierno de la Republica Federal de Alemania. Max Planck Institut Fur Strahlenchemie; Alemania | - |
| dc.description | Fil: Braslavsky, Silvia E.. Gobierno de la Republica Federal de Alemania. Max Planck Institut Fur Strahlenchemie; Alemania | - |
| dc.description | Fil: Indelli, María Teresa. Università di Ferrara; Italia. Consiglio Nazionale delle Ricerche; Italia | - |
| dc.description | Fil: Scandola, Franco. Università di Ferrara; Italia. Consiglio Nazionale delle Ricerche; Italia | - |
| dc.format | application/pdf | - |
| dc.format | application/pdf | - |
| dc.language | eng | - |
| dc.publisher | Elsevier Science | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0009261499013603 | - |
| dc.relation | info:eu-repo/semantics/altIdentifier/doi/https://doi.org/10.1016/S0009-2614(99)01360-3 | - |
| dc.rights | info:eu-repo/semantics/restrictedAccess | - |
| dc.rights | https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ | - |
| dc.source | reponame:CONICET Digital (CONICET) | - |
| dc.source | instname:Consejo Nacional de Investigaciones Científicas y Técnicas | - |
| dc.source | instacron:CONICET | - |
| dc.subject | Otras Ciencias Químicas | - |
| dc.subject | Ciencias Químicas | - |
| dc.subject | CIENCIAS NATURALES Y EXACTAS | - |
| dc.title | Photophysics of supercomplexes. a laser-induced optoacoustic study of the adducts between Ru(bpy)(CN)4 2- and polyaza macrocycles | - |
| dc.type | info:eu-repo/semantics/article | - |
| dc.type | info:eu-repo/semantics/publishedVersion | - |
| dc.type | info:ar-repo/semantics/articulo | - |
| Aparece en las colecciones: | CONICET | |
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